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1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY
Product name: Spinnaker Standard Yacht Varnish
Name : transparent varnish for marine use
Supplier: Cecchi Gustavo & C. srl.
Emergency telephone number : 0584/383694
2. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous ingredients
- Naphta (petroleum) hydrotreated heavy 25-50%
CAS 64742-48-9
EINECS 265-150-3
Xn - R10-65-66
- Xilene £ 2,5 %
CAS 1330-20-7
EINECS 215-535-7
Xn – Xi R10-20/21-38
- 4-(1,1,3,3-tetramethylbutyl)phenol £ 2,5 %
CAS 140-66-9
EINECS 205-426-2
C, N, R34-50/53
- 4-tert-butylphenol£ 2,5 %
CAS 98-54-4
EINECS 202-679-0
Xi, N R36/37/38-51/53
3. HAZARDS IDENTIFICATION
· Hazard description: Not applicable.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid version.
At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
R 10 Flammable.
R 66 Repeated exposure may cause skin dryness or cracking.
· Classification system:
The classification is according to the laextended by company and literature data.
4 First-aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
5 Fire-fighting measures
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents:Water with full jet
· Special hazards caused by the substance, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Carbon monoxide (CO)
· Protective equipment:No special measures required.
6 Accidental release measures
· Person-related safety precautions:
Keep away from ignition sources.
Ensure adequate ventilation
Wear protective equipment. Keep unprotected persons away.
· Measures for environmental protection:
Do not allow to enter sewers/ surface or ground water.
· Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
· Additional information:See Section 7 for information on safe handling.
7 Handling and storage
· Handling:
· Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Storage:
· Requirements to be met by storerooms and receptacles:
Store only in the original receptacle.
· Information about storage in one common storage facility:Not required.
· Further information about storage conditions:Keep container tightly sealed.
8 Exposure controls/personal protection
· Additional information about design of technical facilities:
No further data; see item 7.
· Ingredients with limit values that require monitoring at the workplace:
1330-20-7xylene
OES Short-term value: 662 mg/m³, 150 ppm
Long-term value: 441 mg/m³, 100 ppm
Sk
· Additional information:The lists valid during the making were used as basis.
· Personal protective equipment:
· General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Eye protection:Tightly sealed goggles
· Body protection:Light weight protective clothing
9 Physical and chemical properties
· General Information
Form: Fluid
Colour: According to product specification
Odour: Characteristic
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 150°C
· Flash point: 38°C (DIN 51755)
· Ignition temperature: 240°C
· Self-igniting: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation of explosive air/vapour mixtures are possible.
· Explosion limits:
Lower: 0.6 Vol %
Upper: 7.0 Vol %
· Vapour pressure at 20°C: 1 hPa
· Density at 20°C: 0.91378 g/cm³
· Solubility in / Miscibility with water: Not miscible or difficult to mix.
· Viscosity: Kinematic at 20°C: 50 s (ISO 6 mm)
· Solvent content:
Organic solvents: 38.0 %
VOC content: 38.0 %
376.2 g/l / 3.14 lb/gl
· Solids content: 62.0 % (SC% 1h 150C)
10 Stability and reactivity
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· Dangerous reactionsNo dangerous reactions known.
· Dangerous decomposition products:No dangerous decomposition products known.
11 Toxicological information
· Acute toxicity:
· LD/LC50 values relevant for classification:
64742-48-9Naphtha (petroleum), hydrotreated heavy
Oral LD50 >5000 mg/kg (rat)
Dermal LD50 >3000 mg/kg (rab)
140-66-94-(1,1,3,3-tetramethylbutyl)phenol
Oral LD50 3210 mg/kg (mouse)
· Primary irritant effect:
· on the skin:No irritant effect.
· on the eye:No irritating effect.
· Sensitization:No sensitizing effects known.
12 Ecological information
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
13 Disposal considerations
· Product:
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation:Disposal must be made according to official regulations.
14 Transport information
· Land transport ADR/RID (cross-border)
· ADR/RID class: 3 Flammable liquids.
· UN-Number: 1263
· Packaging group: III
· Hazard label 3
· Description of goods:1263 PAINT
· Maritime transport IMDG:
· IMDG Class: -
· UN Number: 1263
· Marine pollutant: No
· Proper shipping name:PAINT
· Air transport ICAO-TI and IATA-DGR:
· ICAO/IATA Class: 3
· UN/ID Number: 1263
· Label 3
· Packaging group: III
· Proper shipping name:PAINT
15 Regulatory information
· Labelling according to EU guidelines:
Observe the general safety regulations when handling chemicals.
The product has been classified and marked in accordance with EU Directives /
Ordinance on Hazardous Materials.
· Risk phrases:
10 Flammable.
52/53 Harnful to aquatic organism, may cause long-term adverse effects in the aquatic envoronment.
66 Repeated exposure may cause skin dryness or cracking.
· Safety phrases:
2 Keep out of the reach of children.
23 Do not breathe fumes/aerosol.
24 Avoid contact with skin.
29 Do not empty into drains.
46 If swallowed, seek medical advice immediately and show this container or label.
51 Use only in well-ventilated areas.
· Special labelling of certain preparations:
Contains 2-butanone oxime, cobalt carboxylate. May produce an allergic
reaction.
· National regulations:
· Technical instructions (air):
Class Share in %
I 2,5
· Waterhazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information
This information is based on our present knowledge. However, this shall not
constitute a guarantee for any specific product features and shall not
establish a legally valid contractual relationship.
· Relevant R-phrases
10 Flammable.
20/21 Harmful by inhalation and in contact with skin.
34 Causes burns.
36/37/38Irritating to eyes, respiratory system and skin.
38 Irritating to skin.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
Further information The information supplied in this Safety Data Sheet is designed only as guidance for the
safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.
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