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1. Identification
of Substance / Preparation and Company
Trade Name : NAUTILUS EPOXY LIGHT FILLER comp. B
Use of the substance / preparation: Epoxy Filler
Supplier: Cecchi Gustavo & C., Via Coppino 253, Viareggio 55049 (LU)
tel 0039 0584/383694 fax 0039 0584/395182 www.cecchi.it - info@cecchi.it
Information in case of emergency: 0039 0584/383694
2. HAZARDS IDENTIFICATION
Main hazards: Causes burns. May cause sensitisation by skin contact. Possible risk of irreversible effects.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous ingredients:
-LOW BOILING POINT NAPHTHA - UNSPECIFIED - SOLVENT NAPHTHA (PETROLEUM),
LIGHT AROM. 1-10%
EINECS: 265-199-0 CAS: 64742-95-6
[-] R10; [Xi] R37; [N] R51/53; [Xn] R65
- BENZYL ALCOHOL 1-10%
EINECS: 202-859-9 CAS: 100-51-6
[Xn] R20/22
- M-XYLYLENDIAMIN 1-10%
[Xn] R20/22; [C] R34; [Sens.] R43; [-] R52/53
- PHENOL 1-10%
EINECS: 203-632-7 CAS: 108-95-2
[T] R23/24/25; [C] R34; [Xn] R48/20/21/22; [Xn] R68
-DIAMINOPOLYPROPYLENGLYKOL 10-20%
[C] R34
4. FIRST AID MEASURES (SYMPTOMS)
Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.
Eye contact: Corneal burns may occur. May cause permanent damage.
Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding
from the mouth or nose.
Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may cause
coughing or wheezing.
4. FIRST AID MEASURES (ACTION)
Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the
affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer to
hospital if there are burns or symptoms of poisoning.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination.
Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10
minutes. If unconscious, check for breathing and apply artificial respiration if necessary. If
unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious and
breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or lies
down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available.
Transfer to hospital as soon as possible.
5. FIRE-FIGHTING MEASURES
Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.
Exposure hazards: Corrosive. In combustion emits toxic fumes.
Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Notify the police and fire brigade immediately. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised
personnel. Do not attempt to take action without suitable protective clothing - see section 8 of
SDS. Turn leaking containers leak-side up to prevent the escape of liquid.
Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.
Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific substance.
Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by
an appropriate method.
7. HANDLING AND STORAGE
Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air.
Storage conditions: Store in cool, well ventilated area. Keep container tightly closed.
Suitable packaging: Coated steel.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Hazardous ingredients: PHENOL
WEL (8 hr TWA): 2 ppm
Engineering measures: Ensure there is sufficient ventilation of the area.
Respiratory protection: Self-contained breathing apparatus must be available in case of emergency.
Hand protection: Impermeable gloves.
Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.
Skin protection: Impermeable protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
State: Liquid
Colour: Grey
Solubility in water: Not miscible
Also soluble in: Most organic solvents.
Viscosity: Viscous
Boiling point/range°C: n.V.
Melting point/range°C: n.V.
Flammability limits %: lower: n.V.
upper: n.V.
Flash point°C: 100
Part.coeff. n-octanol/water: n.V.
Autoflammability°C: n.a.
Vapour pressure: n.V.
Relative density: 0,5-0,7 g/cm3l
pH: n.a.
VOC g/l: 40
10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions.
Conditions to avoid: Heat.
Materials to avoid: Strong oxidising agents. Strong acids.
Haz. decomp. products: In combustion emits toxic fumes.
11. TOXICOLOGICAL INFORMATION
Hazardous ingredients: LOW BOILING POINT NAPHTHA - UNSPECIFIED - SOLVENT NAPHTHA (PETROLEUM),
LIGHT AROM.
ORL RAT LD50 8400 mg/kg
• BENZYL ALCOHOL
IVN RAT LD50 53 mg/kg
ORL MUS LD50 1360 mg/kg
ORL RAT LD50 1230 mg/kg
• PHENOL
ORL MUS LD50 270 mg/kg
ORL RAT LD50 317 mg/kg
SCU RAT LD50 460 mg/kg
Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms.
12. ECOLOGICAL INFORMATION
Mobility: Readily absorbed into soil.
Persistence and degradability: Biodegradable.
Bioaccumulative potential: No bioaccumulation potential.
Other adverse effects: Negligible ecotoxicity.
13. DISPOSAL CONSIDERATIONS
Waste code number: 08 04 09
Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes.
NB: The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.
14. TRANSPORT INFORMATION
ADR / RID
UN no: 1759 ADR Class: 8
Packing group: II Classification code: C10
Shipping name: CORROSIVE SOLID, N.O.S.
Labelling: 8 Hazard ID no: 80
IMDG / IMO
UN no: 1759 Class: 8
Packing group: II EmS: F-A,S-B
Marine pollutant: .
Labelling: 8
IATA / ICAO
UN no: 1759 Class: 8
Packing group: II
Packing instructions: 814(P&CA); 816(CAO)
Labelling: 8
15. REGULATORY INFORMATION
Hazard symbols: Corrosive.
Risk phrases: R34: Causes burns.
R43: May cause sensitisation by skin contact.
R68: Possible risk of irreversible effects.
Safety phrases: S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S36/37/39: Wear suitable protective clothing, gloves and eye / face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible).
Haz. ingredients (label): M-XYLYLENDIAMIN; PHENOL; DIAMINOPOLYPROPYLENGLYKOL
Seveso II guideline: No
Water hazard class: 2 Classification by VwVwS
Note: The regulatory information given above only indicates the principal regulations specifically
applicable to the product described in the safety data sheet. The user's attention is drawn to
the possible existence of additional provisions which complete these regulations. Refer to all
applicable national, international and local regulations or provisions.
16. OTHER INFORMATION
Risk phrases used in s.3: R10: Flammable.
R37: Irritating to respiratory system.
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R65: Harmful: may cause lung damage if swallowed.
R20/22: Harmful by inhalation and if swallowed.
R34: Causes burns.
R43: May cause sensitisation by skin contact.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
R48/20/21/22: Harmful: danger of serious damage to health by prolonged exposure through
inhalation, in contact with skin and if swallowed.
R68: Possible risk of irreversible effects.
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from
handling or from contact with the above product.
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