1. Identification of Substance / Preparation and Company
Identification of Substance or Preparation
Trade Name : NAUTILUS FAST EPOXY FINE FILLER comp. A
Use of the substance / preparation: Epoxy Filler
Supplier: Cecchi Gustavo & C., Via Coppino 253, Viareggio 55049 (LU)
tel 0039 0584/383694 fax 0039 0584/395182 www.cecchi.it - info@cecchi.it
Information in case of emergency: 0039 0584/383694

2. Composition / Information on Ingredients
Chemical Characterisation:
Synthetic resin(s) and filler(s).
Dangerous Ingredients:

- 1,4-Bis(2,3-epoxypropoxy)butane 5 - 10%
CAS - No.2425-79-8
Index - No.603-072-00-7
EEC - No. 219-371-7
Symbol R - phrases Xn R 20/21-36/38-43

- Reactionproduct : Bisphenol-A- Epichlorhydrin 20 - 35%
CAS - No25068-38-6
Index - No603-074-00-8
Symbol R - phrasesXi, N R 36/38-43-51/53
Remarks: Classification and labelling of a product is indicated under item 15.

3. Hazards Identification
For Humans (additional information is given under item 11) :
Irritating to eyes and skin. May cause sensitization by skin contact.
For the Environment :
Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
For Materials:
None

4. First Aid Measures
Inhalation:
Move out of dangerous area.
Move to fresh air. If symptoms persist, call a physician.
Skin Contact :
Wash off immediately with soap and plenty of water.
If symptoms persist, call a physician.
Eye Contact :
Rinse thoroughly with plenty of water, also under the eyelids.
Obtain medical attention.
Ingestion :
Do not induce vomiting.
Clean mouth with water and drink afterwards plenty of water. Obtain medical attention.
Note to Physician:
Treat symptomatically.
Special Equipment:
n.av.

5. Fire Fighting Measures
Suitable Extinguishing Media : Foam, dry powder, carbon dioxide (CO2), water spray
Extinguishing Media to Avoid : High volume water jet
Fire and Explosion Hazards :
In the event of fire carbon oxides, HCl may be formed.
Additional Information : Cool containers / tanks with spray water.
Special Protective Equipment :
Wear positive pressure self-contained breathing apparatus.
Wear full protective clothing.

6. Accidental Release Measures
Personal Precautions :
See No. 8.3 Personal Protective Equipment. Contaminated surfaces will be extremely slippery.
Ensure adequate ventilation.
Environmental Precautions and Methods for Cleaning up :
Do not flush into surface water or sanitary sewer system. Soak up with inert absorbent material (e.g. sand, silica
gel, acid binder, universal binder, sawdust). Local authorities should be advised if significant spillages cannot be
contained.
Further Information : Respiratory protection

7. Handling and Storage (For national regulations refer to item 15.2)
Handling
Precautions for Safe Handling :
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep at temperature not exceeding 50°C.
Precautions in Case of Fire and Explosion :
Vapours may form explosive mixture with air.
Storage
Storage Instructions :
Jointless smooth floor. Keep away from direct sunlight.
Store away from :
Incompatible with strong acids and oxidising agents.
Further Information on Storage Conditions : Keep away from direct sunlight.
Storage Class : 11 (VCI - Concept)

8. Exposure Controls and Personal Protection
Information on System Design : Provide personal protective equipment.
Exposure Limits:
Material Limit Value :
Personal Protective Equipment
General Protection and Hygiene :
Avoid contact with the skin and the eyes. Do not breathe vapours/dust. When using, do not eat, drink or smoke.
Take off all contaminated clothing immediately.
Respiratory Protection : In case of insufficient ventilation, wear suitable respiratory equipment.
Breathing apparatus with filter. A
Hand Protection : Solvent-resistant gloves (Viton)
Eye Protection : Tightly fitting safety goggles
Skin Protection : Protective suit
Further Information : Refer to special restrictions in wearing protective equipment

9. Physical and Chemical Properties
Appearance
Form : viscous
Colour : white
Odour : not significant
Safety Relevant Data
pH-value, undiluted : n.ap., pH-value, 1% aqueous solution : n.ap.
Boiling point / Boiling - range (°C) : n.av., Melting point / Melting range (°C) : n.av.
Flash point (°C, c.c.) : _ 147
Flammability (EEC A10/A13) : n.av.
Ignition temperature (°C) : n.ap.
Autoflammability (EEC A16) : n.av.
Oxidising properties : n.av.
Explosion hazard : No.
Explosion limits (Vol.%) lower : n.av., upper : n.av.
Vapour pressure : n.av.
Density (g/ml) : 1,8 ± 0,03
Solubility (in Water) : immiscible Miscible with most organic solvents
Partition coefficient, n-Octanol/Water : n.av.
Viscosity : n.av.
Solvent separation test : n.av.
Solvent content (m %) : N.ap.
Further Data
Thermal decomposition (°C) : n.av.
Vapour density (Air = 1) : > 1, (Air = 1.0)
Evaporation rate : n.av.

10. Stability and Reactivity
Conditions to Avoid :
Heat, flames and sparks.
Materials to Avoid :
Incompatible with oxidising agents.
Hazardous Decomposition Products :
None under normal use
Further Information :
None

11. Toxicological Information
Toxicological Tests :
Acute Health Effects :
Inhalation, LC50 rat, (mg/l/4h) : n.av.
Ingestion, LD50 rat, (mg/kg) : n.av.
Skin - contact, LD50 rat, (mg/kg) : n.av.
Irritation (to skin / eye) : Irritating to eyes and skin.
Sensitisation : May cause sensitisation by skin contact.
Subacute / Chronic Toxicity :
Carcinogenicity : n.av.
Mutagenicity : n.av.
Teratogenicity : n.av.
Narcotic Effects : n.av.
Practical Experience
Observations relevant for classification :
None
Further Observations :
None
General Remarks :
Classification of the preparation has been done by calculation in accordance with EEC directives.

12. Ecological Information
Ecotoxic Effects, Aquatic Toxicity :
No information available
Behaviour in Sewage Works :
Mobility and Accumulation Potential : n.av.
Elimination (Persistence and Degradability) :
Decomposes slowly on exposure to water. The product can be degraded by abiotic (e.g. chemical or photolytic)
processes.
Other Ecological Information
COD-Value, mg/g : n.av.
BOD5-Value, mg/g : n.av.
AOX-Remarks : n.av.
Significant Components : n.av.
Other adverse effects : None

13. Disposal Considerations (For national Regulations refer to item 15.)
Residues
Recommendation : D10; R1 Waste - Code - No. : 08 04 09
In addition comply with the regional authorities.
Safe Handling: See item 7 and 15.
Contaminated Packaging
Recommendation : Wash with suitable cleaner. Otherwise as described under Residues.
Safe Handling : As described under Residues.

14. Transport Information
Transportation by Road or Railway according to ADR/GGVS and RID/GGVE
Remarks :
Class : 9 Classification Code : M6 Packing Group : III
Hazard-No. : 90 UN-No. : 3082
Instruction Concerning Shipper's Declaration and Packaging :
Volume or Mass Name and Description Risklabel Packing - Code or instruction
0,5 l n, 12 per box UN 3082 Environmentally hazardous substance, liquid, n.o.s. (Bisphenol-A-Epichlorhydrine-Mixture) n.ap. --/4G
1 l , 12 per box UN 3082 Environmentally hazardous substance, liquid, n.o.s. (Bisphenol-A-Epichlorhydrine-Mixture) n.ap. --/4G
5 l Kanister UN 3082 Environmentally hazardous substance, liquid, n.o.s. (Bisphenol-A-Epichlorhydrine-Mixture) 9 0A1/Z
Classification for Transportation by Inland-Navigation according to ADNO/GGVBinSch
Remarks : Classification has not been done.
Class : Division : Category :
Description of Goods :
Remarks :
Classification for Transportation by Vessels according to IMDG/GGVSee
Remarks :
Class : 9 UN-No. : 3082 Packing Group : III
EmS-No. : None (MFAG-Table : None)
Marine Pollutant : Yes.
Instruction for Declaration and Labelling :
Proper Shipping Name : Environmentally hazardous substance, liquid, n.o.s.
(Bisphenol-A-Epichlorhydrine-Mixture)
Risk Label : Miscellaneous & Marine pollutant
Remarks : None

Classification for Transportation by Aeroplane according to IATA-DGR/ICAO-TI
Remarks :
Class : 9 UN-No. : 3082 Packing Group : III
Instruction for Declaration and Labelling :
(Packing sizes with possible exemptions not considered)
Proper Shipping Name : Environmentally hazardous substance, liquid, n.o.s.
(Bisphenol-A-Epichlorhydrine-Mixture)
Risk Label : Miscellaneous
Packing Instructions, Passenger : 914 Cargo : 914
Remarks : None

15. Regulatory Information
Classification according to EEC-Regulations :
Classification required by EEC : Yes. Applicable Exemptions : No.
Hazard Identification : Irritant & Dangerous for the environment Hazard Symbol(s) :
Component(s) : Contains Bisphenol-A-Epichlorhydrine
R-Phrases :
R36/38 - Irritating to eyes and skin.
R43 - May cause sensitization by skin contact.
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S-Phrases :
S 2 - Keep out of reach of children.
S28 - After contact with skin, wash immediately with plenty of soap and water.
S37/39 - Wear suitable gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
S61 - Avoid release to the environment. Refer to special instructions/Safety data sheets.

Additional Markings :
Contains epoxy constituents. See information supplied by the manufacturer.
The above mentioned labelling is valid for distribution to privat consumers / professional users.
Labelling (formats, exemptions, additional markings) has to be done according to respective regulations.
15.2 National Regulations
VOC-Content:

16. Other Information
Risk Phrases from section 2
R 20/21: Harmful by inhalation and in contact with skin.
R 36/38: Irritating to eyes and skin.
R 43: May cause sensitization by skin contact.
R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
This Material Safety Data Sheet relates to 2001/58/EEC and TRGS 220.
The statements in this Material Safety Data Sheet were made to the best of our knowledge and are as accurate as possible. They are given for information only. They do not constitute a contractual guarantee of a product's properties. They must neither be altered nor transferred to other products.