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1. Identification of the substance
Trade name: EPOXY DRIVE PRIMER CL210 comp. B
Application of the substance: compound for pigment epoxy
Supplier: Cecchi Gustavo & C. srl
Information in case of emergency: 0584/383694
2. HAZARDS IDENTIFICATION
Harmful
Hazardous components which must be listed on the label:
· Xylene
· 2,4,6-Tris(Dimethylaminomethyl)Phenol
· 3,6-Diazaoctaneethylenediamin
R-phrase(s) :
Flammable.
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to respiratory system and skin.
Risk of serious damage to eyes.
May cause sensitization by skin contact.
S-phrase(s) :
Do not breathe spray.
Avoid contact with skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable protective clothing, gloves and eye/face protection.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature : Compound for pigmented epoxy
Hazardous components :
- Xylene >= 15 - < 20
CAS-No. 1330-20-7 EC-No. 601-022-00-9 Symbol(s) Xn R20/21, R38, R10
- Isobutanol >= 15 - < 20
CAS-No. 78-83-1 EC-No. 603-108-00-1 Symbol(s) Xi R10, R41, R67, R37/38
- Diacetone Alcohol >= 3 - < 5
CAS-No. 123-42-2 EC-No. 603-016-00-1 Symbol(s) Xi R36
- 2,4,6-Tris(Dimethylaminomethyl)Phenol >= 7 - < 10
CAS-No. 90-72-2 EC-No. 603-069-00-0 Symbol(s) Xn R22, R36/38
- Methyl Isobutyl Ketone >= 1 - < 3
CAS-No. 108-10-1 EC-No. 606-004-00-4 Symbol(s) F, Xn R11, R20, R66, R36/37
- 2-Methoxy-1-Methylethyl Acetate >= 7 - < 10
CAS-No. 108-65-6 EC-No. 607-195-00-7 Symbol(s) Xi R10, R36
- 3,6-Diazaoctaneethylenediamin >= 1 - < 3
CAS-No. 112-24-3 EC-No. 612-059-00-5 Symbol(s) C R21, R34, R43, R52/53
4. FIRST AID MEASURES
General advice : When symptoms persist or in all cases of doubt seek medical advice.
Never give anything by mouth to an unconscious person.
Inhalation : Remove to fresh air.
Keep patient warm and at rest.
If breathing is irregular or stopped, administer artificial respiration.
If unconscious place in recovery position and seek medical advice.
In case of skin contact : Take off all contaminated clothing immediately.
Wash skin thoroughly with soap and water or use recognized skin cleanser.
Do NOT use solvents or thinners.
Put shower on working place
In case of eye contact : Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart.
Seek medical advice.
Put eye-washer on working place
Remove contact lenses.
If swallowed : If accidentally swallowed obtain immediate medical attention.
Do NOT induce vomiting.
Keep at rest.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.
Keep containers and surroundings cool with water spray.
Extinguishing media which shall not be used for safety reasons
: Do NOT use water jet.
Specific hazards during fire fighting:
As the product contains combustible organic components, fire will produce dense black smoke containing hazardous products of combustion (see section 10).
Exposure to decomposition products may be a hazard to health.
Cool closed containers exposed to fire with water spray.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for fire-fighters: Wear self contained breathing apparatus for fire fighting if necessary.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Solvent vapours are heavier than air and may spread along floors.
Ensure adequate ventilation.
Use personal protective equipment.
Evacuate personnel to safe areas.
Keep people away from and upwind of spill/leak.
Ventilate the area.
Environmental precautions : Try to prevent the material from entering drains or water courses.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods for cleaning up : Clean with detergents. Avoid solvents.
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see
section 13).The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises water (45 parts by volume)/ethanol or isopropanol (50 parts)/ concentrated (d:0,880)ammonia solution (5 parts). A non flammable alternative is sodium carbonate (5 parts)/ water (95 parts).
Pick up and transfer to properly labelled containers.
Clean contaminated surface thoroughly.
Dam up.
Soak up with inert absorbent material and dispose of as hazardous waste.
Additional advice : Refer to section 15 for specific national regulation.
7. HANDLING AND STORAGE
Handling
Safe handling advice : Avoid exceeding of the given occupational exposure limits (see section 8).
Use only in area provided with appropriate exhaust ventilation.
Avoid contact with skin, eyes and clothing.
Smoking, eating and drinking should be prohibited in the application area.
Avoid inhalation of vapour or mist.
For personal protection see section 8.
Thoroughly mix before using
After using, store in a well-sealed container
Advice on protection against fire and explosion
: Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits.
When transferring from one container to another apply earthing measures and use conductive hose material.
No sparking tools should be used.
The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. No smoking.
Storage
Requirements for storage areas and containers
: Observe label precautions.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Solvent vapours are heavier than air and may spread along floors.
Vapours may form explosive mixtures with air.
Electrical installations / working materials must comply with the technological safety standards.
Keep away from sources of ignition - No smoking.
Store between 5° an 35°C in a dry, well ventilated place away from source of heat, ignition and direct sunlight.
Store in accordance with the particular national regulations.
Advice on common storage : Keep away from oxidising agents and strongly acid or alkaline materials.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Xylene CAS-No. 1330-20-7 Value [mg/m3]221,00 Value [ppm]50,00
Isobutanol CAS-No. 78-83-1 Value [mg/m3]152,00 Value [ppm]50,00
Diacetone Alcohol CAS-No. 123-42-2 Value [mg/m3]238,00 Value [ppm]50,00
Methyl Isobutyl Ketone CAS-No. 108-10-1 Value [mg/m3]205,00 Value [ppm]50,00
2-Methoxy-1-Methylethyl Acetate CAS-No. 108-65-6 Value [mg/m3]275,00 Value [ppm]50,00
Personal protective equipment
Respiratory protection : Apply technical measures to comply with the occupational exposure limits.
This should be achieved by a good general extraction and –if practically feasible- by the use of a local exhaust ventilation. If the occupational exposure limits cannot be met, in exceptional
cases suitable respiratory equipment should be worn only for a short period of time.
Hand protection : For prolonged or repeated contact use protective gloves.
Barrier creams may help to protect the exposed areas of skin, they should however not be applied once exposure has occurred.
Skin should be washed after contact.
Wash your hands and put on barrier creams
Eye protection : Chemical resistant goggles must be worn.
Skin and body protection : Skin should be washed after contact.
Working clothes must not consist of textiles, which show a dangerous melting behaviour in case of fire.
Personnel should wear protective clothing
Workers should wear antistatic footwear.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : liquid
Flash point : > 23 - 55 °C
Density : 0,92 g/cm3
Viscosity : <= 60 s
Transversale section: 6 mm
Method: 2431 '84 (ISO 6)
Solids by weight : 49,54 %
Volatile organic compounds
(VOC) content
: 50,45 %
10. STABILITY AND REACTIVITY
Conditions to avoid : Our products were manufactured in compliance with safety standards
to avoid decomposition and degrading under the defined conditions. Taking the product type into account, it is advisable to leave the product in its original packaging thus avoiding transferring it. Hazardous reactions : Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions.
11. TOXICOLOGICAL INFORMATION
Acute inhalation toxicity : Exposure to component solvent vapours concentration in excess of the stated occupational exposure limit may result in adverse health effects.
Such as: mucous membrane irritation, respiratory system irritation, adverse effects on kidney, liver and central nervous system. Symptoms and signs: headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Inhalation of airborne droplets may cause irritation of the respiratory tract.
Skin irritation : Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in desiccation of the skin.
The product may be absorbed through the skin.
Note : The concentration of each substance should be borne in mind in assessing the toxicological effects deriving from the preparation. Isobutanol OBSERVATIONS ON HUMAN SUBJECTS: Exposure through
inhalation causes coughing, irritation to the mucous membranes, dermatitis, headache, dizziness and drowsiness, irritation to the nose, throat and eyes, and the formation of translucent vacuoles on the surface
layer of the cornea.
12. ECOLOGICAL INFORMATION
Further information on ecology : The product contains dangerous substances for the environment (see chapter n° 2), The concentration of each substance should be borne in mind in assessing the toxicological effects deriving from the preparation.
13. DISPOSAL CONSIDERATIONS
Product : The product should not be allowed to enter drains, water courses or the soil.
Disposal together with normal waste is not allowed. Special disposal required according to local regulations.
14. TRANSPORT INFORMATION
ADR : UN-Number 3469
Class 3
Packing instruction (LQ) FC
Packaging group III
Description of the goods PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE
IMDG : UN-Number 3469
Class 3
EmS F-E, S-D
Packaging group III
Description of the goods PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE
IATA UN-Number 3469
Class 3
Packaging group III
Description of the goods PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE
15. REGULATORY INFORMATION
Hazardous components which must be listed on the label:
· Xylene
· 2,4,6-Tris(Dimethylaminomethyl)Phenol
· 3,6-Diazaoctaneethylenediamin
Symbol(s) : Xn Harmful
R-phrase(s) : R10 Flammable.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
S-phrase(s) : S23 Do not breathe spray.
S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
16. OTHER INFORMATION
Further information
Xylene R20/21 Harmful by inhalation and in contact with skin.
R38 Irritating to skin.
R10 Flammable.
Isobutanol R10 Flammable.
R41 Risk of serious damage to eyes.
R67 Vapours may cause drowsiness and dizziness.
R37/38 Irritating to respiratory system and skin.
Diacetone Alcohol R36 Irritating to eyes.
2,4,6-Tris(Dimethylaminomethyl)Phenol
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
Methyl Isobutyl Ketone R11 Highly flammable.
R20 Harmful by inhalation.
R66 Repeated exposure may cause skin dryness or cracking.
R36/37 Irritating to eyes and respiratory system.
2-Methoxy-1-Methylethyl Acetate R10 Flammable.
R36 Irritating to eyes.
3,6-Diazaoctaneethylenediamin R21 Harmful in contact with skin.
R34 Causes burns.
R43 May cause sensitization by skin contact.
R52/53 Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as a guidance for safe handling,
use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid
for such material used in combination with any other materials or in any process, unless specified in the text.
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