1. DESIGNATION OF PRODUCT AND COMPANY
Trade name: C-Systems 10 10 CFS component B
Chemical description: Cycloaliphatic amine based compound
Supplier: Cecchi Gustavo & C., Via Coppino 253, Viareggio 55049 (LU) -
tel 0039 0584/383694 fax 0039 0584/395182 www.cecchi.it - info@cecchi.it

2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components within the meaning of EEC directive 67/548 or with European Community exposure values:
>20% benzyl alcohol
N.67/548/CE: 603-057-00-5 CAS: 100-51-6 EINECS: 202-859-9
Xn Harmful
R20/22 Harmful by inhalation and if swallowed.
<25% 3-aminomethyl-3,5,5-trimethylcyclohexylamine
N.67/548/CE: 612-067-00-9 CAS: 2855-13-2 EINECS: 220-666-8
C Corrosive
R21/22 Harmful in contact with skin and if swallowed.
R34 Causes burns.
R43 May cause sensitization by skin contact.
R50/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
<25% 3,6,9,12-Tetraazatetradecano-1,14-diamina
N.67/548/CE: 612-064-00-2 CAS 4067-16-7 EINECS 223-775-9
C Corrosive
N Dangerous for the environment
R34 provoca ustioni
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

3. HAZARDS IDENTIFICATION
The product is harmful following acute exposure to it and poses a serious health threat if inhaled, ingested, or brought into contact with the skin.
The product is corrosive. If brought into contact with the skin causes burning and in case of contact with eyes may cause damages to the eyelids and to the cornea.
If brought into contact with the skin, the product may cause sensitisation of the skin.
This product is a threat to the environment; it is toxic for aquatic organisms following acute exposure.
In the long term this product may have negative effects on the aquatic environment, because it is not easily biodegradable and/or is bioaccumulable.

4. FIRST-AID MEASURES
Contact with skin:
Immediately take off all contaminated clothing.
Remove the product with a cloth or absorbent paper. Do not use solvents.
Wash with plenty of water and soap.
Consult a physician immediately.
Contact with eyes:
Wash immediately and thoroughly with running water, keeping eyelids raised, for at least 10 minutes. Following this, protect the eyes with sterile gauze or a clean, dry, handkerchief. Obtain a medical examination.
Do not use eyewash or ointment of any kind before obtaining an examination or advice from an ophthalmologist.
Swallowing:
Do not under any circumstances induce vomiting. Obtain a medical examination immediately.
Inhalation:
Ventilate the premises. The patient is to be removed immediately from the contaminated premises to rest in a well ventilated area. Call a physician.

5. FIRE FIGHTING MEASURES
Recommended extinguishers:
CO2, Foam, Chemical powders. Use carefully water based extinguishing media.
Extinguishers not to be used:
None in particular.
Risks arising from combustion:
Avoid inhaling the fumes. Incomplete combustion releases toxic gases.
Protective equipment:
Use protection for the airways.

6. MEASURES IN CASE OF ACCIDENTAL RELEASE
Measures for personal safety:
Use a mask, gloves and protective clothing.
Environmental measures:
Limit leakages with earth or sand.
If the product has escaped into a water course, into the drainage system, or has contaminated the ground or vegetation, notify the competent authorities.
Cleaning methods:
Rapidly recover the product. To do so, wear a mask and protective clothing.
If the product is in a liquid form, stop it from entering the drainage system.
Recover the product for re-use if possible, or for elimination in compliance with waste disposal regulations in force. The product might, where appropriate, be absorbed by inert material.
After the product has been recovered, rinse the involved area and materials with water that must be disposed in compliance with regulations in force.

7. HANDLING AND STORAGE
Handling precautions:
Avoid contact and inhalation of vapours and/or dusts. See, too, paragraph 8 below.
Do not eat or drink or smoke while working. Wash hands before breaks and at the end of work. Provide a correct personal care.
Incompatible materials:
The product reacts with acids, isocyanates, oxidants and epoxy, chlorinated and carbonylic compounds
Storage conditions:
The product is moisture sensitive. Keep in a dry place in the original containers tightly closed.
Instructions as regards storage premises:
Avoid exposition to low temperature (T > 15°C).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Precautionary measures:
Give adequate ventilation to the premises where the product is stored and/or handled.
Respiratory protection:
Required where ventilation/aspiration is insufficient or exposure is prolonged, or applications where heating or spraying are needed.
Protection for hands:
Use protective gloves.
Eye protection:
Safety goggles.
Protection for skin:
Use clothing that provides complete protection to the skin.
Available Exposure Limits (ACGIH) for substances of chapter 2: None

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and colour: Pale yellow liquid
Odour: Amoniacal
pH: 7 About
Flash point: > 100 °C
Specific gravity: 1,02 gr/ml (25°C)
Solubility in water: Miscible
Dynamic viscosity: 400 - 650 mPa.s (25°C)
10. STABILITY AND REACTIVITY
Conditions to avoid:
Stable under normal conditions.
Substances to avoid:
None in particular.
Hazardous decomposition products:
It may generate toxic gases on contact with oxidising mineral acids, halogenated organic substances, organic peroxides and hydroperoxides, and powerful oxidising agents.
During combustion CO, CO2, NH3, NOX and other nitrogen compounds are formed.

11. TOXICOLOGICAL INFORMATION
No toxicological data related to the preparation are available.
When available, the toxicological information relating to the main components are listed below.
3-aminomethyl-3,5,5-trimethylcyclohexylamine
LD50 (oral): > 1.000 mg/kg (rat)
benzyl alcohol
LD50 (oral): > 1.000 mg/kg (rat)
LD50 (dermal): 2.000 mg/kg (rabbit)
LC50 (inhalation): 2000 ppm (4 h, rat)
High vapours concentrations may cause irritation to eyes and to the respiratory system and induce narcosis.

12. ECOLOGICAL INFORMATION
Adopt sound working practices, so that the product is not released into the environment.
When available, the toxicological information relating to the main components are listed below.
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Not expected to be readily biodegradable.
Acute toxicity LC/EC/IC 50: >30 mg/l
benzyl alcohol
Expected to be readily biodegradable.
Acute toxicity TLm/48h/Daphnia: 360 ppm

13. DISPOSAL CONSIDERATIONS
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and national regulations currently in force.

14. TRANSPORT INFORMATION
UN number: 2735
Proper shipping name: POLIAMMINE CORROSIVE, LIQUIDE, NAS (Isophoronediamine) /
POLYAMINES, CORROSIVE, LIQUID, NOS (Isophoronediamine)
Road/Rail (ADR/RID): 8 III
Sea (IMDG): 8-III
Sea (EmS): F-A, S-B
Air (ICAO/IATA): 8-III

15. REGULATORY INFORMATION
European Directives 67/548/CEE, 1999/45/CE and 2001/60/CE (Classification and Labelling):
Symbols:
C Corrosive
N Dangerous for the environment
R Phrases:
R22 Harmful if swallowed.
R34 Causes burns.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrases:
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 After contact with skin, wash immediately with plenty of soaped water.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.
Contents:
benzyl alcohol
3-aminomethyl-3,5,5-trimethylcyclohexylamine
Where applicable, refer to the following regulatory provisions :
Directive 98/24/CE
Directive 91/156/EC; 91/689/EC; 94/62/EC (waste disposal).
Directive 96/82/EC (Seveso Directive).

16. OTHER INFORMATION
Main bibliographic sources:
NIOSH - Registry of toxic effects of chemical substances
ACGIH - Threshold Limit Values (2002)
This PSDS cancels and replaces any previous release.
The information contained herein is based on what we believe to be reliable data, but it is presented without guarantee or warranty by our part and Cecchi Gustavo & C. disclaims any liability incurred from the use thereof.
Nothing contained herein is to be construed as recommendations for use in violation of any existing patent, foreign or domestic, or of applicable laws and regulations.
Apply to Cecchi Gustavo & C. for further information about the product and its use.
It is recommended to pass on this PSDS to customers and handlers.