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1. DESIGNATION
OF PRODUCT AND COMPANY
Trade name C-Systems 10 10 CFS component A
Chemical description: Epoxy resin based compound.
Supplier: Cecchi Gustavo & C., Via Coppino 253, Viareggio 55049 (LU)
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tel 0039 0584/383694 fax 0039 0584/395182 www.cecchi.it - info@cecchi.it
2. COMPOSITION/INFORMATION
ON INGREDIENTS
Hazardous components under the EEC directive 67/548 or components for
which European Community exposure values exists:
> 70% reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number
average molecular weight <= 700)
N.67/548/CE: 603-074-00-8 CAS: 25068-38-6 EINECS: 500-033-5
N Dangerous for the environment
Xi Irritant
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
< 30% Epoxy resin. Reaction product from Bisphenol F-Epichlorohydrin.
CAS: 28064-14-4
Xi Irritant
N Dangerous for the environment
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact.
3. HAZARDS IDENTIFICATION
When brought into contact with the eyes, the product causes irritation
that may last for over 24 hours, and upon brought into contact with the
skin it causes inflammation if it is not removed immediately.
If brought into contact with the skin, the product may cause sensitisation
of the skin.
This product is a threat to the environment; it is toxic for aquatic organisms
following acute exposure.
In the long term this product may have negative effects on the aquatic
environment, because it is not easily biodegradable and/or bioaccumulable.
4. FIRST-AID MEASURES
Contact with skin:
Immediately take off all contaminated clothing.
Remove the product with a cloth or absorbent paper. Do not use solvents.
Wash with plenty of water and soap.
Contact with eyes:
Wash immediately with water for at least 10 minutes.
Seek medical advice if irritation persists.
Swallowing:
The induction of vomiting and the administration of oral drugs must be
carried out only upon medical council.
Inhalation:
Ventilate the premises. The patient is to be removed immediately from
the premises contaminated and made to rest in a well ventilated area.
Should the patient feel unwell, consult a physician.
5. FIRE FIGHTING
MEASURES
Recommended extinguishers:
CO2, Foam, Chemical powders or sand. Use water based extinguishing media
with caution.
Extinguishers not to be used:
None in particular.
Risks arising from combustion:
Avoid inhaling the fumes. Incomplete combustion releases toxic gases.
Protective equipment:
Use protection for the airways.
6. MEASURES IN
CASE OF ACCIDENTAL RELEASE
Measures for personal safety:
Use a mask, gloves and protective clothing.
Environmental measures:
Limit leakages with earth or sand.
If the product has flown off into a water course, into the drainage system,
or has contaminated the ground or vegetation, notify the responsible authorities.
Cleaning methods:
Rapidly collect the product. To do so, wear a mask and protective clothing.
If the product is in a liquid form, stop it from entering the drainage
system.
Recover the product for re-use if possible, or for elimination in compliance
with waste disposal regulations in force. The product might, where appropriate,
be absorbed by inert material.
After the product has been removed, rinse the involved area and materials
with water that must be disposed in compliance with regulations in force.
7. HANDLING AND
STORAGE
Handling precautions:
Avoid contact with and inhalation of vapours and/or dusts. See also paragraph
8 below.
Do not eat or drink or smoke while working. Wash hands before breaks and
at the end of work. Mantain a sufficient personal care.
Incompatible materials:
Keep away from amines, strong bases, acids and strong oxidants.
Storage conditions:
Keep in a dry place, in the original containers tightly closed and avoid
heat sources.
Instructions regarding storage facilities:
Avoid exposition to low temperature (T > 15°C).
8. EXPOSURE CONTROL/PERSONAL
PROTECTION
Precautionary measures:
Provide adequate ventilation to the areas where the product is stored
and/or handled.
Respiratory protection:
Required where ventilation/aspiration is insufficient or exposure is prolonged,
or for applications in which the product is sprayed or heated.
Protection for hands:
Use protective gloves.
Eye protection:
Safety goggles.
Protection for skin:
Use clothing that provides complete protection to the skin.
Available Exposure Limits (ACGIH) for substances of section 2: None
9. PHYSICAL AND
CHEMICAL PROPERTIES
Appearance and colour: violet liquid
Odour: Light
Boiling point: > 200 °C
Flash point: > 150 °C
Combustion-related properties: n.a.
Vapour pressure: n.a.
Specific gravity: 1,14 gr/ml (25°C)
Solubility in water: Insoluble
Partition coefficient (n-octanol/H20) : n.d.
Dynamic viscosity: 600 - 900 mPa.s (25°C)
10. STABILITY AND
REACTIVITY
Conditions to avoid:
Stable under normal conditions.
Substances to avoid:
The product reacts exothermically with amines, Lewis acids and mercaptanes.
Hazardous decomposition products:
It may catch fire on contact with powerful oxidising agents.
Upon incomplete combustion carbon monoxide is formed.
11. TOXICOLOGICAL
INFORMATION
No toxicological data related to the preparation are available.
When available, the toxicological information relating to the main components
are listed below.
reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average
molecular weight <= 700)
LD50 (oral): > 2.000 mg/kg (rat)
LD50 (dermal): > 2.000 mg/kg (rabbit)
Epoxy resin. Reaction product from Bisphenol F-Epichlorohydrin.
LD50 (oral): > 2.000 mg/kg (rat)
LD50 (dermal): > 2.000 mg/kg (rabbit)
12. ECOLOGICAL
INFORMATION
Adopt sound working practices, so that the product is not released into
the environment.
When available, the toxicological information relating to the main components
are listed below.
reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average
molecular weight <= 700)
Sinks in water. Expected to be not readily biodegradable. Has the potential
to bioaccumulate. If product enters soil, it will be mobile and may contaminate
groundwater.
Acute toxicity LC/EC/IC 50 = 1-10 mg/l
Epoxy resin. Reaction product from Bisphenol F-Epichlorohydrin.
Sinks in water. Expected to be not readily biodegradable. Has the potential
to bioaccumulate. If product enters soil, it will be mobile and may contaminate
groundwater.
Acute toxicity LC/EC/IC 50 = 1-10 mg/l
13. DISPOSAL CONSIDERATIONS
Recover if possible. In doing so, comply with the local and national regulations
currently in force.
14. TRANSPORT INFORMATION
UN number: 3082
Proper shipping name: SOSTANZA PERICOLOSA PER L'AMBIENTE, LIQUIDA, NAS
(Resina epossidica)/ ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, NOS
(Epoxy resin)
Road/Rail (ADR/RID): 9 III
Sea (IMDG): 9 - III
Sea (EmS): F-A, S-F
Air (ICAO/IATA): 9-III
15. REGULATORY
INFORMATION
European Directives (Classification and Labelling):
Symbols:
Xi Irritant
N Dangerous for the environment
R Phrases:
R36/38 Irritating to eyes and skin.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
S Phrases:
S28 After contact with skin, wash immediately with plenty of soaped water.
S37/39 Wear suitable gloves and eye/face protection.
S61 Avoid release to the environment. Refer to special instructions/Safety
data sheets.
Special Provisions:
Contains epoxy constituents. See information supplied by the manufacturer.
Contents:
reaction product: bisphenol-A-(epichlorhydrin); epoxy resin (number average
molecular weight <= 700)
Where applicable, refer to the following regulatory provisions :
Directive 98/24/CE
Directive 91/156/EC; 91/689/EC; 94/62/EC (waste disposal).
Directive 96/82/EC (Seveso Directive).
16. OTHER INFORMATION
Main bibliographic sources:
NIOSH - Registry of toxic effects of chemical substances
ACGIH - Threshold Limit Values (2002)
This MSDS cancels and replaces any previous releases.
The information contained herein is based on what we believe to be reliable
data, but it is presented without guarantee or warranty by our part and
Cecchi Gustavo & C. disclaims any liability incurred from the use
thereof.
Nothing contained herein is to be construed as recommendations for use
in violation of any existing patent, foreign or domestic, or of applicable
laws and regulations.
Apply to Cecchi Gustavo & C. for further information about the product
and its use. It is recommended to pass on this MSDS to customers and handlers.
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